Chemistry Letters p. 941 - 942 (1982)
Update date:2022-07-29
Topics:
Kawasaki, Yoshikane
Yokota, Wataru
Enomoto, Norihide
Monophenylthallium(III) complexes with a Tl-I or Tl-SR bond were prepared in the presence of dibenzo-18-crown-6.These complexes are stable in the air and to heat to their melting points.In the hydrogen sulfide complex, ν(S-H) band was found at 2570 cm-1 and δ(Tl-SH) was observed at 1.15 ppm with 2J(Tl-SH)=405 Hz in CH2Cl2 solution.
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(1982)
