83039-93-4Relevant academic research and scientific papers
NEW SYNTHESIS OF METHYL 2-TRIORGANOSILYL-3-BUTENOATES AS A NEW SYNTHON OF 3-METHOXYCARBONYLALLYL ANION
Naruta, Yoshinori,Uno, Hidemitsu,Maruyama, Kazuhiro
, p. 961 - 964 (2007/10/02)
Methyl 2-triorganosilyl-3-butenoates, which are selectively obtained from the carboxylation of the corresponding allylsilanes via allylic aluminates, react with various kinds of electrophiles to give γ substituted (E)-α,β-unsaturated esters in highly regio- and stereoselective manner with the aid of a Lewis acid.
