83076-78-2Relevant academic research and scientific papers
The synthesis of binucleating polyaza macrocyclic and macrobicyclic ligands and the dioxygen affinities of their cobalt complexes
Chen, Dian,Motekaitis, Ramunas J.,Murase,Martell, Arthur E.
, p. 77 - 88 (2007/10/02)
The synthesis of a new macrobicyclic (cryptand) ligand 1,4,9,12,19,20,25,30-octaazabicyclo(10.10.10)dotriacontane, C4BISTREN and improved syntheses of the ligands 7,9,30,trioxa-1,4,10,13,16,22,-27,33-octaazabicyclo(11.11.11)pentatria contane, OBISTREN and 1,13-dioxa-4,7,10,16,19,22-hexaazacyclotetracosane, OBISDIEN. The Co(II) complexes of these ligands are oxygen carriers. Among the six macrocyclic and six macrobicyclic ligands that are considered in this paper, the binuclear cobalt(II) complexes of OBISTREN and OBISDIEN form the most stable dioxygen complexes.
Ditopic Ligands. Synthesis and Complexation Properties of a Pyridine-containing Macrocyclic Hexa-amine, 'Pyridine-N6O2'
Parker, David
, p. 1129 - 1131 (2007/10/02)
The synthesis of a 'pyridine-N6O2' macrocycle (1) is described; it forms 1:1 complexes with zinc, cobalt, and nickel and dinuclear complexes with platinum, palladium, and rhodium.
