83078-43-7Relevant academic research and scientific papers
BENZYNE-INDUCED FRAGMENTATION REACTIONS OF 1,3-DITHIOLANES
Nakayama, Juzo,Ozasa, Hiroshi,Hoshino, Masamatsu
, p. 1053 - 1056 (2007/10/02)
2-Monosubstituted 1,3-dithiolanes, on reaction with benzyne, undergo two types of fragmentation, one of which gives phenyl vinyl sulfide and thioaldehydes (corresponding aldehydes as the final products) and the other gives phenyl dithiocarboxylates and et
Preparation and Some Reactions of Bis(thioacyl) Sulfides
Kato, Shinzi,Shibahashi, Hiroshi,Katada, Tomonori,Takagi, Takashi,Noda, Ippei,et al.
, p. 1229 - 1244 (2007/10/02)
Reaction of dithioic acids with dicyclohexylcarbodiimide has been found to give the corresponding bis(thioacyl) sulfides 1 in good yield, which are very useful thioacylating reagents under mild reaction conditions.Most of the aromatic thioanhydrides (1, R = aromatic) are fairly stable green crystals at room temperature, but the aliphatic ones (1, R = aliphatic) are unstable purple oils which dimerize at room temperature to give the dithietanes 5.The reactions with nucleophiles are discussed.
