831-56-1Relevant academic research and scientific papers
Palladium(II)-catalyzed ortho-arylation of benzylic phosphonic monoesters using potassium aryltrifluoroborates
Meng, Xiangjian,Kim, Sunggak
, p. 11247 - 11254 (2013/12/04)
The new monophosphonic acid directing group was successfully utilized in the Pd (II)-catalyzed ortho-arylation of benzylic phosphonic monoesters using potassium aryltrifluoroborates. A wide range of benzylic phosphonic monoesters underwent clean ortho-ary
Dialkyl phosphonates and tetraalkyl bis(phosphonate)s from the decomposition of quasi-phosphonium ylidic phosphonates in aqueous conditions
Griffiths, D. Vaughan,Karim, Khalku,Harris, Jayne E.
, p. 2539 - 2544 (2007/10/03)
The reaction of dimethyl benzoylphosphonates 1 (X = 2-halogen or 2-CF3O) with trialkyl phosphite leads to the formation of carbene intermediates 3 which are trapped by trialkyl phosphite to give the corresponding ylidic phosphonates 4. In acidi
