52242-71-4Relevant academic research and scientific papers
New Group 9 metal complexes containing N,P-chelate ligand system.: Synthesis, characterization and application to catalytic hydrogenation
Lee, Heung-Sae,Bae, Jin-Young,Ko, Jaejung,Kang, Yong Soo,Kim, Hoon Sik,Kim, Sung-Joon,Chung, Jang-Hoon,Kang, Sang Ook
, p. 83 - 91 (2007/10/03)
New N,P-chelating o-carboranylaminophosphine ligand CabN,P 2 [CabN,P=o-C2B10H10(CH 2NMe2)(PPh2)-N,P] was prepared from o-carboranylamine LiCabN [CabN=o-C2B10H10(CH 2NMe2)-N] and chlorodiphenylphosphine. Consequently, the reaction of [M(cod)(solv)2]+BF4- (M=Rh, Ir; cod=cycloocta-1,5-diene) with 2 was investigated. The resulting rhodium and iridium metal complexes [(CabN,P)M(cod)]+BF4- 3 (M=Rh 3a, Ir 3b) were characterized by NMR spectroscopy and elemental analysis. In addition, an X-ray structure analysis was performed on complex 3a, where the potential N,P-chelate ligand 2 was found to coordinate in a bidentate mode. The subsequent reaction of 3 with PPh3 and CO resulted in the dissociation of the N,P-chelate ligand 2 to yield the penta-coordinate metal complexes [(PPh3)2M(CO)3]+BF4 - 4 (M=Rh 4a, Ir 4b). The structure of 4a was determined by X-ray diffraction analysis, exhibiting a trigonal bipyramidal configuration with the triphenylphosphine ligands occupying axial positions. The activities of complex 3 as a catalyst precursor during the hydrogenation of cyclohexene were tested and produced the cyclohexane with 100% conversion in the case of 3a.
THE REACTION OF TRIHYDROBISTRIPHENYLPHOSPHINE IRIDIUM IrH3(PPh3)2 WITH DIAZONIUM SALTS
Angoletta, Maria,Caglio, Giorgio
, p. 99 - 106 (2007/10/02)
The reaction of IrH3(PPh3)2 with p-substituted aryldiazonium salts gives the compounds +BF4- at low temperature (-10 deg C) and the o-metalated complexes (R=F, OCH3) at 40-50 deg C.The reactions of the o-metalated complexes with CO, PPh3, NaI and HCl have been studied.
