83160-40-1

Basic information

• Product Name: methyl 4-O-benzoyl-6-bromo-6-deoxy-2-O-p-tolylsulfonyl-α-D-glucopyranoside
• Synonyms: methyl 4-O-benzoyl-6-bromo-6-deoxy-2-O-p-tolylsulfonyl-α-D-glucopyranoside
• CAS NO: 83160-40-1
• Molecular Weight: 515.379
• Mol File: 83160-40-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 4-O-benzoyl-6-bromo-6-deoxy-2-O-p-tolylsulfonyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4-O-benzoyl-6-bromo-6-deoxy-2-O-p-tolylsulfonyl-α-D-glucopyranoside(83160-40-1)
• EPA Substance Registry System: methyl 4-O-benzoyl-6-bromo-6-deoxy-2-O-p-tolylsulfonyl-α-D-glucopyranoside(83160-40-1)

Safety Data

• Hazardous Substances Data: 83160-40-1(Hazardous Substances Data)

Upstream product

• 6698-32-4 methyl 4,6-O-benzylidene-2-O-toluene-p-sulfonyl-α-D-glucopyranoside 

Downstream Products

• 83160-41-2 Benzoic acid (2R,3S,4S,5R,6S)-2-but-3-enyl-4-hydroxy-6-methoxy-5-(toluene-4-sulfonyloxy)-tetrahydro-pyran-3-yl ester 

Relevant articles and documents

The formation of branched-chain deoxypentofuranosides by ring contraction in the reductive desulfonyloxylation of hexopyranoside p-toluenesulfonates

Several methyl 6-deoxy-, 6-deoxy-6-halo-, and 6-O-p-tolylsulfonylhexopyranoside 2- and 4-p-toluenesulfonates reacted readily with lithium triethylborohydride in boiling tetrahydrofuran under reductive desulfonyloxylation at C-2 and C-4, respectively, and