6698-32-4

Upstream product

• 3162-96-7 methyl 4,6-O-benzylidene-α-D-glucopyranoside 
• 2232-08-8 N-tosylimidazole 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 6752-49-4 (4aR,6S,8aR)-6-Methoxy-2-phenyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-8-one 
• 40773-64-6 methyl 4,6-O-benzylidene-3-deoxy-ribo-hexopyranoside 
• 3169-98-0 methyl 4,6-O-benzylidene-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside 
• 3051-92-1 methyl 4,6-O-benzylidene-α-D-ribohexopyranosid-3-ulose 
• 16848-76-3 methyl 4,6-O-benzylidene-2,3-dideoxy-α-D-erythro-hexopyranoside 
• 76143-38-9 Toluene-4-sulfonic acid (4aR,6S,7R,8aR)-8-hydrazino-8-hydroxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 
• 4153-14-4 methyl 4,6-O-benzylidene-2-O-p-toluenesulphonyl-α-D-allopyranoside 
• 34266-73-4 methyl 4,6-O-benzylidene-3-deoxy-α-D-arabino-hexopyranoside 
• 73683-73-5 methyl 4,6-O-benzylidene-3-deoxy-3-C-methyl-α-D-glucopyranoside 
• 77516-58-6 methyl 4,6-O-benzylidene-3-deoxy-3-C-methyl-α-L-arabino-hexopyranosid-2-ulose 
• 20702-73-2 methyl 4,6-O-benzylidene-3-deoxy-3-C-methyl-α-D-ribo-hexopyranosid-2-ulose 
• 5987-36-0 methyl 4,6-O-benzylidene-3-deoxy-3-C-methyl-α-D-altropyranoside 
• 83160-40-1 methyl 4-O-benzoyl-6-bromo-6-deoxy-2-O-p-tolylsulfonyl-α-D-glucopyranoside 
• 4234-42-8 methyl 4,6-O-benzylidene-2-O-p-toluenesulphonyl-α-D-ribohexopyranosid-3-ulose 

Relevant academic research and scientific papers

Assignment of the absolute configuration of blasticidin A and revision of that of aflastatin A

The absolute configuration of blasticidin A, a strong inhibitor of aflatoxin production by Aspergillus parasiticus, was assigned by adding the data of relative configurations at its diol and pentaol moieties to previously known stereochemistry. Similarity

Silver(I) oxide mediated selective monoprotection of diols in pyranosides

The reaction of 4,6-O-benzylidene-D-pyranosides with a stoichiometric amount of TsCl, AcCl, and BzCl in the presence of silver(I) oxide and a catalytic amount of potassium iodide led to monosubstituted derivatives in high regioselectivity and in good yiel

Regioselective acylation of carbohydrates with 1-acyloxy-1H-benzotriazoles

Acylation of representative carbohydrate derivatives was accomplished with in situ generated 1-acyloxy-1H-benzotriazoles. The observed high regioselectivity, mild reaction conditions and convenient work-up make the presented one-pot procedure generally applicable and more advantageous than acylations with previously introduced reagents, including N-acylimidazoles.