83168-66-5

Usage

Uses

Used in Electronics Industry:
(E,Z)-(CF3CF=CF)2 is used as an insulating gas for its high thermal and chemical stability, which helps protect sensitive electronic components from heat and chemical reactions that could cause damage or malfunction.
Used in Refrigeration Industry:
In the refrigeration industry, (E,Z)-(CF3CF=CF)2 serves as a refrigerant due to its non-flammability and low toxicity, making it a safer and more environmentally friendly alternative to traditional refrigerants.
Used as a Fire Extinguishing Agent:
(E,Z)-(CF3CF=CF)2 is utilized as a fire extinguishing agent because of its non-flammable nature and ability to displace oxygen, effectively smothering fires without causing further harm or damage to the environment.
Used in Chemical Manufacturing:
(E,Z)-(CF3CF=CF)2 is also employed in chemical manufacturing processes as a heat transfer fluid, taking advantage of its high thermal stability to maintain consistent temperatures during various chemical reactions and processes.

InChI:InChI=1/C6F10/c7-1(3(9)5(11,12)13)2(8)4(10)6(14,15)16/b3-1-,4-2+

Upstream product

• 356-35-4 Perfluoro-1,5-hexadiene 
• 431-65-2 perfluoroallyl iodide 
• 89031-87-8 perfluoro-cis-3,4-dimethylcyclobutene 
• 102682-88-2 perfluoropropenylcopper 
• 102682-82-6 (Z)-perfluoropropenyl iodide 

Relevant academic research and scientific papers

Transformations of F-Alkyl Iodides and Bromides Induced by Nickel(0) Carbonyl

Adducts of primary F-alkyl iodides with nickel carbonyl are formed readily in donor solvents and pyrolyze at 100-150 °C to give olefinic coupling products in high yield. The mechanism proposed to account for the observed chemistry involves preferential α-elimination of fluorine with formation of a carbenoid species complex coordinated to nickel. Differences in reaction paths among several types of substrate halides are rationalized on the basis of polarization of the Ni-C bond in the adducts. Support for these proposals is provided by state-of-the-art calculations.

Kinetic and Thermodynamic Studies of the Thermal Electrocyclic Interconversions of Perfluorinated Dienes and Cyclobutenes

Detailed kinetic and thermodynamic analyses were carried out for the thermal interconversions of (Z,Z)- and (E,E)-perfluoro-2,4-hexadienes with trans-perfluoro-3,4-dimethylcyclobutene, (E,Z)-perfluoro-2,4-hexadiene with perfluoro-cis-3,4-dimethylcyclobutene, (Z,Z)- and (E,E)-perfluoro-3,5-octadienes with trans-perfluoro-3,4-diethylcyclobutene, and (Z)- and (E)-perfluoro-1,3-pentadiene with perfluoro-3-methylcyclobutene.In each case the (Z,Z)- or (Z)-dienes exhibited substantial kinetic advantage over the (E,E)-or (E)-dienes in their cyclization precesses.