83168-86-9Relevant academic research and scientific papers
SILAFUNCTIONAL COMPOUNDS IN ORGANIC SYNTHESIS. XVIII. OXIDATIVE CLEAVAGE OF THE SILICON-CARBON BOND IN ALKENYLFLUOROSILANES TO CARBONYL COMPOUNDS: SYNTHETIC AND MECHANISTIC ASPECTS
Tamao, Kohei,Akita, Munetaka,Kumada, Makoto
, p. 13 - 22 (2007/10/02)
Alkenyltrifluorosilanes are readily oxidized by one equivalent of MCPBA in DMF even at -50 deg C to give the corresponding carbonyl compounds via cleavage of the carbon-silicon bond.With three equivalent of MCPBA a concomitant cleavage of the carbon-carbon bond occurs.A plausible mechanism of these new types of oxidation has been discussed.Oxidation with DABCO*2H2O2 has also been described.
