83178-27-2Relevant academic research and scientific papers
Organometallic rotaxanes with a triazole group in the axle component and their behavior as ligands of PtII complexes
Yu, Gilbert,Suzaki, Yuji,Abe, Tomoko,Osakada, Kohtaro
, p. 207 - 213 (2012)
Two ferrocenylmethyl ammonium salts were used as axle components of pseudorotaxanes with dibenzo[24]crown-8. The pseudorotaxane with an alkyne terminal group in the axle component underwent a Cu-catalyzed Huisgen coupling reaction (click reaction) with an alkyl azide to afford cationic [2]rotaxanes with a triazole group in the axle molecule. The rotaxane reacted with Ac 2O to produce neutral rotaxanes with an amide group in the axle component. Both cationic and neutral rotaxanes were treated with K[PtCl 3(CH2=CH2)] to form the PtII- containing rotaxanes.
