83182-07-4Relevant academic research and scientific papers
Studies on the selective hydrolysis of bis-dithiolanes with cerric ammonium nitrate: synthesis of 1,4-dithiaspirodecan-7-ones
Nangia, A.,Chandrakala, P. S.
, p. 516 - 519 (2007/10/03)
Dimedone 10 is directly ketalised with ethanedithiol to bis dithiolane 11 using Dean-Stark conditions.The selective hydrolysis of bis-dithiolane 11 to the ketodithiolane 12 employing cerric ammonium nitrate (CAN) proceeds in 35percent yield under optimal conditions.A few examples are reported.
