83205-05-4Relevant academic research and scientific papers
Platinum-catalyzed nucleophilic addition of vinylsilanes at the β-position
Miura, Katsukiyo,Inoue, Gen,Sasagawa, Hisashi,Kinoshita, Hidenori,Ichikawa, Junji,Hosomi, Akira
supporting information; experimental part, p. 5066 - 5069 (2009/12/28)
In the presence of catalytic amounts of PtCl2 and metal Iodides, β-substituted vlnylsllanes reacted with aldehydes at the β-position to give allyl silyl ethers. The Pt-catalyzed addition to aromatic aldehydes proceeded efficiently in the presence of Lil. The combined use of PtCl 2 and Mnl2 was found to be effective In addition to aliphatic aldehydes.
REGIOCHEMISTRY AND STEREOCHEMISTRY OF OXIRANE RING-OPENING WITH SILYL HALIDES
Detty, Michael R.,Seidler, Mark D.
, p. 2543 - 2546 (2007/10/02)
The ring-opening of various styrene and stilbene oxides with silyl halides was examined.The regiochemistry of ring-opening was independent of the silyl halide used, but the stereochemistry of ring-opening was sensitive to both the choice of halide and the steric bulk of groups attached to silicon.
