83207-71-0

Upstream product

• 86302-43-4 (tert-Butoxycarbonylmethylene)triphenylphosphorane 
• 102-92-1 Cinnamoyl chloride 
• 107-59-5 tert-Butyl chloroacetate 
• 1262551-94-9 C₃₀H₃₆O₆P₂ 
• 100-52-7 benzaldehyde 
• 603-35-0 triphenylphosphine 

Downstream Products

• 83199-93-3 tert-butyl 4-methyl-3-oxo-5-phenyl-2-(triphenylphosphoranylidene)nonanoate 
• 83199-89-7 tert-butyl 3-oxo-5-phenyl-2-(triphenylphosphoranylidene)pentanoate 
• 83199-96-6 3-Benzyl-4-phenyl-pentan-2-one 
• 83199-98-8 3-methyl-4-phenyl-2-octanone 
• 83199-91-1 tert-butyl 4-benzyl-3-oxo-5-phenyl-2-(triphenylphosphoranylidene)hexanoate 

Relevant academic research and scientific papers

A new synthesis of triphenylphosphorane ylide precursors to α-keto amide/ester and tricarbonyl units via horner-wadsworth-emmons reaction

Newly developed Horner-Wadsworth-Emmons (HWE) reagents 5 having triphenylphosphorane ylide subunits readily condensed with various carbonyl compounds under mild reaction conditions to afford β,γ-unsaturated α-keto triphenylphorane ylides in good to excell

Charge-Directed Conjugate Addition Reactions in the Preparation of Substituted Methyl Ketones

Charge-directed conjugated addition reactions of the tert-butyl esters of α,β-unsaturated acylphosphoranes 2 have been used to prepare a variety of substituted methyl ketones.Substituted ylides 6 are prepared by alkylating ylide anions 4 generated by the addition of nucleophiles to 2 and are converted under acidic conditions to substituted (acylmethylene)phosphoranes 12 which are hydrolyzed to methyl ketones.The utility of these unsaturated acylphosphoranes as methyl vinyl ketone equivalents in conjugate addition-alkylation reactions is demonstrated in a synthesis of the racemic form of the sex pheromone of the California red scale, 14.