832079-44-4Relevant academic research and scientific papers
Synthesis and characterizations of free base and Cu(II) complex of a porphyrin sheet
Nakamura, Yasuyuki,Aratani, Naoki,Furukawa, Ko,Osuka, Atsuhiro
scheme or table, p. 11433 - 11439 (2009/04/11)
Free base porphyrin sheet 5 was prepared by demetalation of zinc complex 1, which was now more conveniently prepared in 30% yield by oxidation of a mixture of tetraporphyrins, 8, 9, and 11. The 1H NMR spectrum of 5 shows no indication of an aromatic ring current for the porphyrin rings and evidences the freezing of the pyrrolic NH protons at the most inner and outer corner positions, both of which contrast sharply with strong aromatic ring currents and rapid NH tautomerism of normal porphyrins. DFT calculations supported the experimental results, suggesting that the enforced planar COT core causes these unique properties. The free base 5 was transformed into Cu(II) complex 6 that exhibits antiferromagnetic interaction among the Cu(II) ions with J=-1.16 cm-1.
