83210-45-1

Upstream product

• 15529-49-4 tris(triphenylphosphine)ruthenium(II) chloride 
• 106-93-4 ethylene dibromide 
• 17534-15-5 Benzene-1,2-dithiol 
• 83209-89-6 1,2-bis(2-mercaptophenylthio)ethane 

Downstream Products

• 83210-47-3 Ru⁽²⁺⁾*N₂H₄*P(C₆H₅)3*(SC₆H₄SCH₂CH₂SC₆H₄S)^(2-) = [Ru(N₂H₄)(P(C₆H₅)3)(SC₆H₄SCH₂CH₂SC₆H₄S)] 
• 83210-46-2 [Ru(CO)(P(C₆H₅)3)(SC₆H₄SCH₂CH₂SC₆H₄S)] 

Relevant academic research and scientific papers

Transition Metal Complexes with Sulfur Ligands, XXVII. Synthesis and Reactivity of the Nitrosyl- and Nitrido-Ruthenium Complexes with 1,2-Benzenedithiolate Ligands (-) and (-), Respectively

The reaction of , PF6 or with 1,2-benzenedithiolate(-2), C6H4S2(2-), leads to the 16e(-)-complex (-), which was isolated as the NBu4(+) salt (1).The square pyramidal anion in Ru(

Syntheses and Reactions of Sulfur Coordinated Ruthenium Complexes

The syntheses and reactions of sulfur coordinated ruthenium centers with CO, PR3, (R = Me, ), N2H4 and N2 are investigated.Reaction of with lithium-o-methylthiobenzenethiolate yields cis-, with Li2-o-benzenedithiolate the cis-(2-)-ion is obtained, which can be isolated either as the NMe4 salt or reacted further with 1,2-C2H4Br2 to give cis-, (dttd(2-) = 2,3,8,9-Dibenzo-1,4,7,10-tetrathiadecane(2-)).In all three complexes the CO ligands are relatively inert to substitution; refluxing of (2-) in EtOH in the presence of excess PMe3, however, and subsequent alkylation with 1,2-C2H4Br2 yields . is obtained from and Li2-dttd, the synthesis of which is also described.In the PMe3 ligands are inert, but in 3)2(dttd)> one P3 ligand is easily substituted by CO or N2H4 yielding 3)dttd> or 3)dttd> respectively; 3)2(dttd> is obtained from 3)3Cl2> and H2-dttd.The complexes are characterized by elemental analyses, IR, 1H NMR and mass spectroscopy. - Key words: Ruthenium Sulfur Carbonyl Phosphine Hydrazine Complexes