83216-10-8

Basic information

• Product Name: (1S,βR)-4-Carboxy-5-[[(1S,4S)-3,3-dimethyl-2-oxo-7-oxabicyclo[2.2.1]heptan-1-yl]methyl]-2,6,7,7a-tetrahydro-7β-hydroxy-β,1,7aα-trimethyl-1H-indene-1α-propanoic acid
• Synonyms: (1S,βR)-4-Carboxy-5-[[(1S,4S)-3,3-dimethyl-2-oxo-7-oxabicyclo[2.2.1]heptan-1-yl]methyl]-2,6,7,7a-tetrahydro-7β-hydroxy-β,1,7aα-trimethyl-1H-indene-1α-propanoic acid;Glycinoeclepin A
• CAS NO: 83216-10-8
• Molecular Formula: C₂₅H₃₄O₇
• Molecular Weight: 446.5333
• Mol File: 83216-10-8.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 607.2°Cat760mmHg
• Flash Point: 202.2°C
• Appearance: /
• Density: 1.27g/cm³
• Vapor Pressure: 2.81E-17mmHg at 25°C
• Refractive Index: 1.573
• CAS DataBase Reference: (1S,βR)-4-Carboxy-5-[[(1S,4S)-3,3-dimethyl-2-oxo-7-oxabicyclo[2.2.1]heptan-1-yl]methyl]-2,6,7,7a-tetrahydro-7β-hydroxy-β,1,7aα-trimethyl-1H-indene-1α-propanoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,βR)-4-Carboxy-5-[[(1S,4S)-3,3-dimethyl-2-oxo-7-oxabicyclo[2.2.1]heptan-1-yl]methyl]-2,6,7,7a-tetrahydro-7β-hydroxy-β,1,7aα-trimethyl-1H-indene-1α-propanoic acid(83216-10-8)
• EPA Substance Registry System: (1S,βR)-4-Carboxy-5-[[(1S,4S)-3,3-dimethyl-2-oxo-7-oxabicyclo[2.2.1]heptan-1-yl]methyl]-2,6,7,7a-tetrahydro-7β-hydroxy-β,1,7aα-trimethyl-1H-indene-1α-propanoic acid(83216-10-8)

Safety Data

• Hazardous Substances Data: 83216-10-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C25H34O7/c1-13(10-19(27)31-5)15-6-7-16-20(21(28)29)14(11-17(26)24(15,16)4)12-25-9-8-18(32-25)23(2,3)22(25)30/h7,13,15,17-18,26H,6,8-12H2,1-5H3,(H,28,29)/t13-,15-,17-,18-,24+,25+/m1/s1

Upstream product

• 562-13-0 2,2-dimethyl-1,3-cyclohexanedione 

Downstream Products

• 96890-26-5 Glycinoeclepin A Bis-(p-bromophenacyl) Ester 

Relevant articles and documents

Asymmetric total synthesis of glycinoeclepin A: Generation of a novel bridgehead anion species

The asymmetric total synthesis of glycinoeclepin A, a hatchstimulating agent of the soybean, cyst nematode, was accomplished on the basis of a cyclopentene annulation for constructing the CD ring moiety having contiguous quaternary carbon atoms. Introduction of the A ring moiety was achieved by an alkylation reaction using a 7-oxabicyclo[2.2.1]hex-l-yl anion species.