83223-83-0

Upstream product

• 106836-88-8 1-(2,4-dichlorophenyl)-2,2-dimethoxyethanone 
• 105459-84-5 2,4-dichlorophenyl magnesium iodide 
• 77315-52-7 α-Methoxy-α-(1H-1,2,4-triazol-1-yl)aceton 
• 676-58-4 methylmagnesium chloride 
• 105459-80-1 2,4-Dichlor-α-methoxy-α-(1H-1,2,4-triazol-1-yl)acetophenon 

Relevant academic research and scientific papers

Use of diphenyl ether derivatives for the desiccation and abscission of plant organs

The use of diphenyl ether derivatives of the general formula I STR1 where A is a radical STR2 where R1 is hydrogen, an alkali metal or alkaline earth metal ion, substituted or unsubstituted ammonium, alkyl of from 1 to 4 carbon atoms or alkoxycarbonylalkyl of a total of 1 to 6 carbon atoms and R2 is alkyl of from 1 to 4 carbon atoms, for the desiccation and abscission of plant organs.

Chelation-Controlled Grignard Reactions of &α-(1H-1,2,4-Triazol-1-yl) Ketones

The high diastereoselectivity of the Grignard addition to α-(1H-1,2,4-triazol-1-yl) ketones (1,4), α-alkoxy-α-(1H-1,2,4-triazol-1-yl) ketones (7,13) and corresponding imidazolyl derivatives can be rationalized via postulated intermediate chelate complexes 3,9.In this case, alkoxy groups as well as azole substituents may function as ligands.For 2d and 8d an X-ray structural analysis was performed.