83236-50-4

Basic information

• Product Name: 1H-Cyclopenta[b]pyridine-3-carbonitrile, 4-(4-chlorophenyl)-2,5,6,7-tetrahydro-2-thioxo-
• CAS NO: 83236-50-4
• Molecular Formula: C15H11ClN2S
• Molecular Weight: 286.785
• Mol File: 83236-50-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1H-Cyclopenta[b]pyridine-3-carbonitrile, 4-(4-chlorophenyl)-2,5,6,7-tetrahydro-2-thioxo-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Cyclopenta[b]pyridine-3-carbonitrile, 4-(4-chlorophenyl)-2,5,6,7-tetrahydro-2-thioxo-(83236-50-4)
• EPA Substance Registry System: 1H-Cyclopenta[b]pyridine-3-carbonitrile, 4-(4-chlorophenyl)-2,5,6,7-tetrahydro-2-thioxo-(83236-50-4)

Safety Data

• Hazardous Substances Data: 83236-50-4(Hazardous Substances Data)

Upstream product

• 1867-38-5 4-chlorobenzylidenemalonodinitrile 
• 1687-46-3 cyclopentane-1,1-dithiol 
• 83236-47-9 7-Amino-9-(4-chloro-phenyl)-6,10-dithia-spiro[4.5]dec-7-ene-8-carbonitrile 
• 7357-70-2 Cyanothioacetamide 
• 134791-44-9 (E)-2-(4-chlorobenzylidene)cyclopentan-1-one 
• 936-52-7 1-(N-morpholino)cyclopent-1-ene 
• 102423-75-6 2,6-diamino-4-(4-chlorophenyl)-4H-thiopyran-3,5-dicarbonitrile 

Downstream Products

• 345912-24-5 4-(4-chloro-phenyl)-2-cyanomethylsulfanyl-6,7-dihydro-5H-[1]pyrindine-3-carbonitrile 
• 345912-36-9 3-amino-4-(4-chloro-phenyl)-6,7-dihydro-5H-1-thia-8-aza-s-indacene-2-carbonitrile 
• 345912-33-6 2-[4-(4-chloro-phenyl)-3-cyano-6,7-dihydro-5H-[1]pyrindin-2-ylsulfanyl]-N-p-tolyl-acetamide 
• 345912-45-0 3-amino-4-(4-chloro-phenyl)-6,7-dihydro-5H-1-thia-8-aza-s-indacene-2-carboxylic acid p-tolylamide 
• 345912-32-5 N-(4-chloro-phenyl)-2-[4-(4-chloro-phenyl)-3-cyano-6,7-dihydro-5H-[1]pyrindin-2-ylsulfanyl]-acetamide 
• 536720-16-8 [4-(4-chloro-phenyl)-3-cyano-6,7-dihydro-5H-[1]pyrindin-2-ylsulfanyl]-acetic acid ethyl ester 
• 434293-29-5 3-amino-4-(4-chloro-phenyl)-6,7-dihydro-5H-1-thia-8-aza-s-indacene-2-carboxylic acid ethyl ester 
• 536720-22-6 2-carbamoylmethylsulfanyl-4-(4-chlorophenyl)-6,7-dihydro-5H-[1]pyrindine-3-carbonitrile 
• 434293-37-5 3-amino-4-(4-chloro-phenyl)-6,7-dihydro-5H-1-thia-8-aza-s-indacene-2-carboxylic acid amide 
• 488824-03-9 2-methoxycarbonylmethylsulfanyl-4-(4-chlorophenyl)-6,7-dihydro-5H-[1]pyrindine-3-carbonitrile 
• 1414778-32-7 ethyl 4-(4-bromophenyl)-6-({[4-(4-chlorophenyl)-3-cyano-6,7-dihydro-5H-cyclopenta[b]pyridin-2-yl]thio}methyl)-1-methyl-2-oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate 
• 1414778-34-9 ethyl 6-({[4-(4-chlorophenyl)-3-cyano-6,7-dihydro-5H-cyclopenta[b]pyridin-2-yl]thio}methyl)-4-(4-methoxyphenyl)-1-methyl-2-oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate 
• 345912-44-9 3-amino-4-(4-chloro-phenyl)-6,7-dihydro-5H-1-thia-8-aza-s-indacene-2-carboxylic acid (4-chloro-phenyl)-amide 
• 345912-43-8 3-amino-4-(4-chloro-phenyl)-6,7-dihydro-5H-1-thia-8-aza-s-indacene-2-carboxylic acid phenylamide 

Relevant articles and documents

Cross-recyclization of 4-aryl-2,6-diamino-4H-thiopyran-3,5-dicarbonitriles with 1-morpholino-1-cyclopentene: New route to 4-aryl-2-thioxo-2,5,6,7- tetrahydro-1H-[1]pyrindine-3-carbonitriles and their derivatives

Reaction of 4-aryl-2,6-diamino-4H-thiopyran-3,5-dicarbonitriles with 1-morpholino-1-cyclopentene led to the formation of 4-aryl-2-thioxo-2,5,6,7- tetrahydro-1H-[1]pyrindine-3-carbonitriles used in the synthesis of substituted 2-alkylsulfanyl-4-aryl-6,7-di

CYCLIZATION OF NITRILES. X. ENAMINO NITRILES OF THE 1,3-DITHIA-4-CYCLOHEXENE SERIES AND THEIR RECYCLIZATION TO DERIVATIVES OF PYRIDINE AND THIAZOLE

The recyclization of 4-amino-6-aryl-5-cyano-2-cyclopentane(cyclohexane)spiro-1,3-dithia-4-cyclohexenes, obtained from gem-dithiols and arylidenemalononitriles, leads to the formation of 4-aryl-5,6-polymethylene-3-cyano-2-(1H)-pyridinethiones.The latter are used in the synthesis of various 3-aminothienopyridines, 4-aryl-3-amino-5,6,7,8-tetrahydrothienoquinolines, and other heterocyclic compounds condensed with quinoline. 1-Cyano-1-(4-aryl-2-thiazolyl)-2-arylethylenes were obtained by the reaction of the 1,3-dithia-4-cyclohexenes with phenacyl bromides.