83251-41-6Relevant academic research and scientific papers
Quantitative ortho-Cycloboronation of P-Phenyl Groups in Metallaborane Chemistry and the Crystal and Molecular Structure of the Novel iso-closo-Ten-vertex Metallaborane
Bould, Jonathan,Greenwood, Norman N.,Kennedy, John D.,McDonald, Walter S.
, p. 465 - 467 (1982)
High-yield ortho-cycloboronation reactions of P-phenyl groups on phosphine ligands in iridadecaboranes accompany both nido cluster expansion and nido -> closo cluster closing processes that are associated with changes in the formal oxidation state of the metal atom; one of the products has a novel iso-closo-ten-vertex iridium(V) metallaborane cluster structure of idealized C3v symmetry (IrB3B3B3).
