Journal of the Chemical Society. Chemical communications p. 465 - 467 (1982)
Update date:2022-08-05
Topics:
Bould, Jonathan
Greenwood, Norman N.
Kennedy, John D.
McDonald, Walter S.
High-yield ortho-cycloboronation reactions of P-phenyl groups on phosphine ligands in iridadecaboranes accompany both nido cluster expansion and nido -> closo cluster closing processes that are associated with changes in the formal oxidation state of the metal atom; one of the products has a novel iso-closo-ten-vertex iridium(V) metallaborane cluster structure of idealized C3v symmetry (IrB3B3B3).
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