83267-90-7Relevant articles and documents
1-Methyl-4-ferrocenylmethyl-3,5-diphenylpyrazole: A versatile ligand for palladium(II) and platinum(II)
Basu, Pradipta Kumar,González, Asensio,López, Concepción,Font-Bardía, Mercè,Calvet, Teresa
, p. 3633 - 3642 (2010/01/11)
The syntheses and characterization of two novel ferrocene derivatives containing 3,5-diphenylpyrazole units of general formula [1-R-3,5-Ph2-(C3N2)-CH2-Fc] {Fc = (η5-C5H5)Fe(ηsup
Ferrocenyl salts as synthons: new ferrocenyl-1,3-diketones
Zakaria, Choudhury M.,Morrison, Colin A.,McAndrew, Douglas,Bell, William,Glidewell, Christopher
, p. 201 - 208 (2007/10/02)
Reaction of (ferrocenylmethyl)trimethylammonium iodide with the mono-sodium salts of a range of acyclic 1,3-diketones leads smoothly to 2-(ferrocenylmethyl)-1,3-diketones CH(COR1)(COR2), but with the corresponding tetrabutylammonium salts deacylation occurs.With the sodium salt of cyclohexane-1,3-dione, disubstitution occurs to give (2,6-dioxocyclohexane-1,1-diyl)bismethyleneferrocene, 2C.The lithium salt of acetylferrocene reacts with a range of monocarboxylic esters to provide 1-ferrocenyl-1,3-diketones COCH2COR, but simple esters of dicarboxylic acids either do not react, or undergo only monosubstitution. Keywords: Ferrocene; Diketones; Iron