dibenzoyl(ferrocenylmethyl)methane

Base Information

• Chemical Name: dibenzoyl(ferrocenylmethyl)methane
• CAS No.: 83267-90-7
• Molecular Formula: C₂₆H₂₂FeO₂
• Molecular Weight: 422.306
• Mol file: 83267-90-7.mol

Synonyms:dibenzoyl(ferrocenylmethyl)methane

Chemical Property of dibenzoyl(ferrocenylmethyl)methane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dibenzoyl(ferrocenylmethyl)methane

There total 4 articles about dibenzoyl(ferrocenylmethyl)methane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-ferrocenylmethanol (1273-86-5) + 1,3-diphenylpropanedione (120-46-7,61346-73-4) → dibenzoyl(ferrocenylmethyl)methane (83267-90-7)

Guidance literature:

With HClO₄ or HBF₄; In dichloromethane; byproducts: H2O; aq. HClO4 (70 %) or HBF4 (45 %) added to the Fe-complex and the ketone;soln. stirred (30 min, 20°C), addn. of ether; ether soln. washed twice (water), dried (sodium sulfate), solvent removed (vac.), recrystn. (hexane/ethyl acetate 1:1); elem. anal.;

Reference yield: 92.0%

N,N,N-(ferrocenylmethyl)trimethylammonium iodide + 1,3-diphenylpropanedione (120-46-7,61346-73-4) → dibenzoyl(ferrocenylmethyl)methane (83267-90-7)

Guidance literature:

In N,N-dimethyl-formamide; boiling an equimolar mixt. of (PhCO)2CH2 and complex for 1 h in soln.; thin-layer chromy.; elem. anal.;

DOI:10.1016/0022-328X(85)87277-6

Reference yield: 75.0%

N,N,N-(ferrocenylmethyl)trimethylammonium iodide + sodium dibenzoylmethane (19269-14-8) → dibenzoyl(ferrocenylmethyl)methane (83267-90-7)

Guidance literature:

In acetonitrile; reflux (15 h); removal of solvent, dissoln. in dry CH2Cl2, filtration; elem. anal.;

DOI:10.1016/0022-328X(94)24775-E

upstream raw materials:

1-ferrocenylmethanol

1,3-diphenylpropanedione

sodium dibenzoylmethane

Downstream raw materials:

[1-H-3,5-Ph2-(C3N2)-CH2-(η5-C5H5)Fe(η5-C5H4)]