83313-00-2Relevant academic research and scientific papers
CATALYTIC INTRAMOLECULAR 2-(4-ALKENYL)ALLYLPALLADIUM INSERTIONS
Oppolzer, Wolfgang,Swenson, Rolf E.,Gaudin, Jean-Marc
, p. 5529 - 5532 (1988)
Pd(O)-catalyzed cyclizations of 1-acetoxy-2-methylene-6-heptenes(34, 1819) are consistent with a allylpalladium/olefin insertion involving a metal-transfer to the distal alkene terminal.Cyclization 78 exemplifies a new stereocontrolled access to
