Tetrahedron Letters p. 5529 - 5532 (1988)
Update date:2022-08-04
Topics:
Oppolzer, Wolfgang
Swenson, Rolf E.
Gaudin, Jean-Marc
Pd(O)-catalyzed cyclizations of 1-acetoxy-2-methylene-6-heptenes(3<*>4, 18<*>19) are consistent with a allylpalladium/olefin insertion involving a metal-transfer to the distal alkene terminal.Cyclization 7<*>8 exemplifies a new stereocontrolled access to
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