CATALYTIC INTRAMOLECULAR 2-(4-ALKENYL)ALLYLPALLADIUM INSERTIONS

DOI: 10.1016/S0040-4039(00)80804-7

Source and publish data:

Tetrahedron Letters p. 5529 - 5532 (1988)

Update date:2022-08-04

Topics:

Authors:

Oppolzer, Wolfgang

Swenson, Rolf E.

Gaudin, Jean-Marc

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Article abstract of DOI:10.1016/S0040-4039(00)80804-7

Pd(O)-catalyzed cyclizations of 1-acetoxy-2-methylene-6-heptenes(3<*>4, 18<*>19) are consistent with a allylpalladium/olefin insertion involving a metal-transfer to the distal alkene terminal.Cyclization 7<*>8 exemplifies a new stereocontrolled access to

Full text of DOI:10.1016/S0040-4039(00)80804-7

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