83318-94-9

Upstream product

• 108-98-5 thiophenol 
• 7306-46-9 4-chloromethyl-1,2-dimethoxy-benzene 
• 93-03-8 (3,4-dimethoxyphenyl)methanol 
• 21852-32-4 4-bromomethyl-1,2-dimethoxybenzene 
• 120-14-9 3,4-dimethoxy-benzaldehyde 
• 882-33-7 diphenyldisulfane 
• 76950-89-5 1-(3,4-Dimethoxy-benzyl)-4,6-diphenyl-1H-pyridine-2-thione 
• 930-69-8 sodium thiophenolate 
• 83319-05-5 2-Benzylsulfanyl-1-(3,4-dimethoxy-benzyl)-4,6-diphenyl-pyridinium; bromide 

Downstream Products

• 19819-29-5 2-(3,4-Dimethoxyphenyl)tetrahydrofuran 
• 103844-19-5 3-hydroxymethyl-6,7-dimethoxy-1-(3',4'-methylenedioxyphenyl)-4β-phenylthio-1,2,3,4-tetrahydro-2-naphthoic acid γ-lactone 
• 103844-19-5 3-hydroxymethyl-6,7-dimethoxy-1-(3',4'-methylenedioxyphenyl)-4α-phenylthio-1,2,3,4-tetrahydro-2-naphthoic acid γ-lactone 
• 103844-18-4 4-(3',4'-dimethoxyphenyl)-3-hydroxymethyl-6,7-methylenedioxy-3,4-dihydro-2-naphthoic acid γ-lactone 
• 10352-26-8 3,4,3',4'-tetramethoxy-9,9'-epoxylignan 
• 118535-07-2 3-(3'',4''-dimethoxy-α-phenylthiobenzyl)-2-(α-hydroxy-3',4'-methylenedioxybenzyl)-γ-butyrolactone 
• 132636-00-1 (-)-(3S,4R,5R,6R,7S)-3-(3',4'-methylenedioxy-α-hydroxybenzyl)-4-<3'',4''-dimethoxy-α-(phenylthio)benzyl>-5-(1-menthyloxy)butyrolactone 
• 132697-68-8 (+)-(3S,4R,5R,6R,7R)-3-(3',4'-methylenedioxy-α-hydroxybenzyl)-4-<3'',4''-dimethoxy-α-(phenylthio)benzyl>-5-(1-menthyloxy)butyrolactone 

Relevant academic research and scientific papers

Unusual cleavage of ethers by thiophenol on the surface of silica gel impregnated with indium(III) chloride under microwave irradiation: Efficient procedure for the synthesis of thioethers through transthioetherification

Cyclic and open-chain benzylic ethers undergo cleavage by thiophenol on the surface of silica gel impregnated with indium(III) chloride under microwave irradiation to produce the corresponding di- and monothioethers.

Dithioacetalization or thioetherification of benzyl alcohols using 9-mesityl-10-methylacridinium perchlorate photocatalyst

We report herein the use of 9-mesityl-10-methylacridinium perchlorate as the visible-light photocatalyst for dithioacetalization or thioetherification of benzyl alcohols in one pot using aerial dioxygen as a terminal oxidant. EPR analysis and Stern-Volmer

Visible-Light-Induced Cyclization of Electron-Enriched Phenyl Benzyl Sulfides: Synthesis of Tetrahydrofurans and Tetrahydropyrans

A new approach to the preparation of tetrahydrofurans and tetrahydropyrans through a photoredox catalytic process is described. The introduction of a phenylsulfanyl auxiliary group permits the substrates to be readily oxidized to form cationic intermediates for sequential intramolecular cyclization. The method features mild reaction conditions and operational simplicity.

Camphorquinone: A new and efficient oxidant for the preparation of 2-thio-substituted benzothiazoles from alcohols by oxidation-reduction condensation

A convenient one-pot procedure for the preparation of various 2-thio-substituted benzothiazoles from alcohols and benzothiazole-2-thiol utilizing camphorquinone-mediated oxidation-reduction condensation is disclosed. The condensation between benzothiazole-2-thiol and alkyl diphenylphosphinites, generated in situ from alcohols and chlorodiphenylphosphine, proceeded smoothly in the presence of camphorquinone to furnish the corresponding benzothiazoles in good to moderate yields.

A SHORT VERSATILE SYNTHESIS OF ARYLTETRALIN LIGNANS INCLUDING DEOXYISOPODOPHYLLOTOXIN AND EPI-ISOPODOPHYLLOTOXIN

Cyclisation of tandem conjugate addition products (10), (15), and (20), prepared by reaction of anions derived from benzyl phenyl and benzyl t-butyl sulphides with but-2-en-4-olide, affords a series of aryltetralin lignans belonging to either the 'normal' or the 'retro' lactone series.Desulphurisation of compound (15) followed by cyclisation, or desulphurisation of the cyclised product (22b), affords deoxyisopodophyllotoxin (5), while treatment of compound (22b) with mercury(II) trifluoroacetate yields epi-isopodophyllotoxin (6).