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Undecacarbonyl(tris(4-methylphenyl)phosphino)triruthenium is a complex organometallic compound with the chemical formula [Ru3(CO)11(P(C6H4CH3)3)] and a molecular weight of 1,003.47 g/mol. It consists of three ruthenium atoms, eleven carbonyl ligands, and one tris(4-methylphenyl)phosphine ligand. undecacarbonyl (tris(4-methylphenyl)phosphino) triruthenium is known for its unique structure and potential applications in homogeneous catalysis, particularly in the field of olefin metathesis and hydrogenation reactions. The tris(4-methylphenyl)phosphino ligand provides steric and electronic properties that can influence the reactivity and selectivity of the complex. The compound is typically synthesized through the reaction of ruthenium carbonyl clusters with tris(4-methylphenyl)phosphine, and it is often used as a precursor for the preparation of other ruthenium-based catalysts.

83343-69-5

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83343-69-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 83343-69-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,3,3,4 and 3 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 83343-69:
(7*8)+(6*3)+(5*3)+(4*4)+(3*3)+(2*6)+(1*9)=135
135 % 10 = 5
So 83343-69-5 is a valid CAS Registry Number.

83343-69-5Downstream Products

83343-69-5Relevant academic research and scientific papers

Syntheses, structure characterisation and X-ray structures of the complexes Ru3(CO)11L [L = Ph2P(C6H 4Me-p), Ph2PC6F5, P(C 6H4Cl-p)3,

Shawkataly, Omar Bin,Pankhi, Mohd. Aslam A.,Fun, Hoong-Kun,Yeap, Chin Sing

, p. 2667 - 2673 (2011/01/10)

Five trinuclear monosubstituted complexes of the type Ru 3(CO)11L were synthesised by the reaction of Ru 3(CO)12 with phosphine ligands (L) using the radical anion catalysed method. The structures of the resulti

CLUSTER CHEMISTRY. XVII. RADICAL ION-INITIATED SYNTHESES OF RUTHENIUM CLUSTER CARBONYLS CONTAINING TERTIARY PHOSPHINES, PHOSPHITES, ARSINES, SbPh3 OR ISOCYANIDES

Bruce, Michael I.,Matisons, Janis G.,Nicholson, Brian K.

, p. 321 - 344 (2007/10/02)

The syntheses of over sixty known and new derivatives of Ru3(CO)12 and H4Ru4(CO)12 by substitution reactions initiated by sodium diphenylketyl are described.The range of ligands studied includes isocyanides, tertiary phosphines and phosphites, tertiary ar

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