83379-11-7Relevant academic research and scientific papers
Terpenes and Terpenoid Cmpounds, 15. - Preparation of Tetramethylated Perillyl Alcohol and Related
Pauluth, Detlef,Hoffmann, H. M. R.
, p. 403 - 412 (2007/10/02)
Lithium perchlorate-induced rearrangement of 1,3,3,5,5-pentamethyl-4-(1-methylethenyl)-7-oxabicycloheptane (2) in toluene furnishes the epimeric tetramethylated dihydrocarvones 4t, c and 2,2,4,4-tetramethyl-6-methylene-3-(1-methylethenyl)-trans-cyc
Homologues of Monocyclic Monoterpenes. Tetramethylated Derivatives of Carvone, Carveol, β-Terpineol, Sobrerol, and Related Compounds
Giguere, Raymond J.,Ilsemann, Godard von,Hoffmann, H. M. R.
, p. 4948 - 4954 (2007/10/02)
Epoxidation of tetramethyllimonene (1) gave monoepoxide 2t, which was opened regioselectively to endo and exo tetramethylated trans-carveols 3t and 5t, respectively.The alcohols were further oxidized to tetramethylcarvone (4) and its unstable exocyclic is
