83379-16-2

Upstream product

• 68930-33-6 tetramethyl-limonene (3,3,5,5-tetramethyl-p-mentha-1,8-diene) 
• 83379-10-6 1,1,3,3-tetramethyl-5-methylene-2-(1-methylethenyl)cyclohexane 
• 84602-70-0 1,3,3,5,5-Pentamethyl-4-(1-methylethenyl)chlorocyclohexane 
• 113831-05-3 cis-1-hydroxymethyl-3,3,5,5-tetramethyl-4-(1-methylethenyl)cyclohexane 

Downstream Products

• 113831-10-0 (Z)-1-(3-hydroxypropyl)-3,3,5,5-tetramethyl-4-(1-methylethenyl)-1-cyclohexanol 
• 113831-25-7 (Z)-1-(3-hydroxy-1-propynyl)-3,3,5,5-tetramethyl-4-(1-methylethenyl)-1-cyclohexanol 
• 16556-46-0 3,3,5,5-Tetramethyl-4-acetyl-1-cyclohexanon 
• 83379-14-0 cis-1,3,3,5,5-pentamethyl-4-(1-methylethenyl)cyclohexan-1-ol 

Relevant academic research and scientific papers

Regio- and Stereoselective Transformations of 3,3,5,5-Tetramethylcyclohexane Derivatives Oxygenations, Annulations, and SN2'-Reactions

Hydroboration of TM-Δ1,7-methadiene (4) (TM = tetramethyl) with 9-BBN gave TM-cis-shisool (cis-5), which was converted into TM-trans-shisool (trans-5) via the aldehyde cis-7, base-catalyzed epimerization to trans-7, and finally LiAlH4 reduction

Terpenes and Terpenoid Cmpounds, 14. - Synthesis of Oxygenated Derivatives in the Tetramethyllimonene Series. - New Odorants of the Wood-Ambergris Type

A practical preparation of TM-α-terpineol (4), cis-TM-β-terpineol (6c), trans-TM-β-terpineol (6t), TM-Δ1,7,Δ8-menthadiene (7), its spirocyclic epoxide (5), and TM-isocryptone (8) is described (TM = tetramethyl).Some of the new tetram

Homologues of Monocyclic Monoterpenes. Tetramethylated Derivatives of Carvone, Carveol, β-Terpineol, Sobrerol, and Related Compounds

Epoxidation of tetramethyllimonene (1) gave monoepoxide 2t, which was opened regioselectively to endo and exo tetramethylated trans-carveols 3t and 5t, respectively.The alcohols were further oxidized to tetramethylcarvone (4) and its unstable exocyclic is