68930-33-6

Usage

Synthesis Reference(s)

Tetrahedron Letters, 25, p. 1567, 1984 DOI: 10.1016/S0040-4039(01)90012-7

InChI:InChI=1/C14H24/c1-10(2)12-13(4,5)8-11(3)9-14(12,6)7/h8,12H,1,9H2,2-7H3

Upstream product

• 1000-86-8 2,4-Dimethyl-1,3-pentadiene 
• 141-79-7 4-methyl-pent-3-en-2-one 
• 74-88-4 methyl iodide 
• 60-29-7 diethyl ether 
• 846549-58-4 4-bromo-2,4-dimethyl-pent-1-ene 
• 75-16-1 methylmagnesium bromide 
• 1000-87-9 2,4-dimethyl-2,3-pentadiene 
• 64-18-6 formic acid 
• 84602-70-0 1,3,3,5,5-Pentamethyl-4-(1-methylethenyl)chlorocyclohexane 
• 917-64-6 methyl magnesium iodide 
• 84050-67-9 2,4-dimethyl-4-chloro-2-pentene 
• 98-83-9 isopropenylbenzene 

Downstream Products

• 81517-76-2 (1S,3R)-3-Isopropenyl-2,2,4,4-tetramethyl-6-methylene-cyclohexanol 
• 81517-78-4 2,2,4,4-tetramethyl-6-methylene-3-(1-methylethenyl)-cyclohexanone 
• 81517-80-8 TM-cis-carveol 
• 81517-75-1 TM-trans-carveol 
• 81517-77-3 5-isopropenyl-2,4,4,6,6-pentamethyl-2-cyclohexenone 
• 81517-76-2 2,2,4,4-tetramethyl-6-methylene-3-(1-methylethenyl)-trans-cyclohexan-1-ol 
• 102608-67-3 2,2,4,4-tetramethyl-6-methylene-3-(1-methylethenyl)-cyclohexan-1-ol 
• 83379-21-9 TM-sobrerol 
• 83379-22-0 3-<1-(hydroxymethyl)ethenyl>-2,2,4,4-tetramethyl-6-methylenecyclohexanol 
• 96850-41-8 rac-2-(2,2,4,6,6-Pentamethyl-3-cyclohexenyl)-1-propansaeure 
• 99474-98-3 2-(2,2,4,6,6-Pentamethyl-3-cyclohexenyl)-1-propanal 
• 96850-37-2 rac-2-(2,2,4,6,6-Pentamethyl-3-cyclohexenyl)-1-propanol 
• 96850-35-0 rac-2-(3-Hydroxy-2,2,4,6,6-pentamethylcyclohexyl)-1-propanol 
• 96850-36-1 rac-2-(4-Hydroxy-2,2,4,6,6-pentamethylcyclohexyl)-1-propanol 

Relevant academic research and scientific papers

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The series of 2,2,6,6-tetramethyl-1-isopropenylcyclohexenes 2-6 shows hindered rotation of the isopropenyl group, the activation barrier ΔG(excit.) varying from 12.8 to >15.7 kcal/mol.Splitting patterns and chemical shifts of the olefinic protons of the i

Homologues of Monocyclic Monoterpenes. Tetramethylated Derivatives of Carvone, Carveol, β-Terpineol, Sobrerol, and Related Compounds

Epoxidation of tetramethyllimonene (1) gave monoepoxide 2t, which was opened regioselectively to endo and exo tetramethylated trans-carveols 3t and 5t, respectively.The alcohols were further oxidized to tetramethylcarvone (4) and its unstable exocyclic is

Cycloadditions of Allyl Cations. 25. Acid Catalyzed Dehydrative Cyclodimerization of 2,4-Dimethyl-3-penten-2-ol in Two Phases. Biomimetic One-Pot Preparation of 3,3,5,5-Tetramethyllimonene (4-Isopropenyl-1,3,3,5,5-pentamethyl-1-cyclohexene)

2,4-Dimethyl-3-penten-2-ol (1) wurde in einer Mischung von waessriger Sulfonsaeure/Pentan bei Raumtemperatur geruehrt.Es bildete sich 3,3,5,5-Tetramethyllimonen (2) in hoher Ausbeute. 2 wurde in sein Epoxid (3) (4-Isopropenyl-1,3,3,5,5-pentamethyl-7-oxabicycloheptan) umgewandelt.