83399-63-7

Upstream product

• 67120-85-8 (E)-1-Methoxy-3-trimethylsilyloxy-penta-1,3-dien 
• 100-52-7 benzaldehyde 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 83416-30-2 tert-Butyl-[(E)-1-((E)-2-methoxy-vinyl)-propenyloxy]-dimethyl-silane 
• 56279-28-8 (1E)-1-methoxypent-1-en-3-one 
• 65648-53-5 1-Methoxy-3-trimethylsilyloxy-1,3-pentadein 

Downstream Products

• 106929-95-7 Acetic acid (2S,3R,4R)-3-methyl-2-phenyl-3,4-dihydro-2H-pyran-4-yl ester 
• 106930-03-4 (2S,3R,6S)-3-Methyl-6-((R)-1-methyl-allyl)-2-phenyl-3,6-dihydro-2H-pyran 
• 106930-04-5 (2S,3R,6S)-3-Methyl-6-((S)-1-methyl-allyl)-2-phenyl-3,6-dihydro-2H-pyran 
• 76549-03-6 methyl (2S,3S)-3-hydroxy-2-methyl-3-phenylpropanoate 
• 76549-02-5 (-)-(2S,3S)-3-hydroxy-2-methyl-3-phenylpropanoic acid 

Relevant academic research and scientific papers

Enantio- and diastereoselective hetero-Diels-Alder reactions between 4-methyl-substituted Rawal's diene and aldehydes catalyzed by chiral dirhodium(II) carboxamidates: Catalytic asymmetric synthesis of (-)-cis-aerangis lactone

The first catalytic asymmetric hetero-Diels-Alder (HDA) reaction between 3-tert-butyldimethylsilyloxy- 1-dimethylamino-1,3-pentadiene (4-methyl-substituted Rawal's diene) and aldehydes is described. With 3 mol % of dirhodium(II) tetrakis[N-benzene-fused-p

A Concise and Stereoselective Route to the Predominant Stereochemical Pattern of the Tetrahydropyranoid Antibiotics: An Application to Indanomycin

The reactions of (E)- and (Z)-crotylsilanes of the type R3Si-CH2-CH=CH-CH3 with activated glycal derivatives in the presence of BF3 etherate have been examined.In all cases, the reactions were regiospecific, resulting in incorporation of a 3-methylprop-1-