83413-27-8Relevant articles and documents
Bimetallic η6,η1-and PCP-pincer ruthenium palladium complexes: Synthesis, structure, and catalytic activity
Bonnet, Sylvestre,Lutz, Martin,Spek, Anthony L.,Van Koten, Gerard,Klein Gebbink, Robertus J. M.
, p. 1157 - 1167 (2010)
The synthesis of η6,η1 SCS- and PCP-pincer ruthenium palladium complexes [3]+-[6]+ by direct η6-coordination of [Ru(C5R5)]+ (R = H or Me) to the arene ring of η1
Palladium pincer complex catalyzed cross-coupling of vinyl epoxides and aziridines with organoboronic acids
Kjellgren, Johan,Aydin, Juhanes,Wallner, Olov A.,Saltanova, Irina V.,Szabo, Kalman J.
, p. 5260 - 5268 (2007/10/03)
Palladium-catalyzed crosscoupling of vinyl epoxides and aziridines with organoboronic acids was performed by using 0.5-2.5 mol % pincer-complex catalyst. The reactions proceed under mild conditions affording allyl alcohols and amines with high regioselectivity and in good to excellent yields. Under the applied reaction conditions aromatic chloro-, bromoand iodo substituents are tolerated. Our results indicate that the mechanism of the pincer complex catalyzed and the corresponding palladium(O) catalyzed process is substantially different. It was concluded that the transformations proceed via transmetalation of the organoboronic acids to the pincercomplex catalyst followed by an S N2′type opening of the vinyl epoxide or aziridine substrate. In this process the palladium atom is kept in oxidation state +2 under the entire catalytic process, and therefore oxidative side reactions can be avoided.
PALLADIUM CATALYZED COUPLING OF ORGANOSTANNANES WITH VINYL EPOXIDES
Tueting, David R.,Echavarren, Antonio M.,Stille, J. K.
, p. 979 - 992 (2007/10/02)
The coupling reaction of organotin reagents with vinyl epoxides, catalyzed by palladium, takes place at ambient temperatures, regioselectively, giving predominately the 1,4-addition product.Both aryl- and vinylstannanes undergo coupling in high yields, wh
