88154-01-2

Upstream product

• 17902-47-5 trans-1-phenyl-2-(dichloromethylsilyl)ethene 
• 75-54-7 Dichloromethylsilane 
• 536-74-3 phenylacetylene 
• 1199-93-5 β-(dichloromethylsilyl)styrene 

Downstream Products

• 163976-68-9 1(E)-hexa-1,4-dienylbenzene 
• 109898-19-3 (E)-(3-methylpenta-1,4-dien-1-yl)benzene 
• 72045-17-1 5-<(E)-2-phenylethenyl>-2'-deoxyuridine 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 530-48-3 1,1-Diphenylethylene 
• 103-30-0 (E)-1,2-diphenyl-ethene 
• 35225-79-7 dibenzylideneacetone 
• 3988-77-0 2-cinnamoylthiophene 
• 886-65-7 trans,trans-1,4-Diphenyl-1,3-butadiene 
• 83413-35-8 (2E,5E)-6-phenylhexa-2,5-dien-1-ol 
• 83413-27-8 (E)-4-phenyl-2-vinylbut-3-en-1-ol 
• 114467-58-2 (E)-(HOCH₂)(CH₃)C(CHCH₂)CHCHPh 
• 26057-47-6 (E,E)-1,5-diphenyl-1,4-pentadiene 
• 21502-38-5 (1E,4E)-1-phenyl-1,4-hexadiene 

Relevant academic research and scientific papers

Cross-coupling and carbonylative cross-coupling of organofluorosilanes with hypervalent iodonium tetrafluoroborates

The palladium-catalyzed cross-coupling and carbonylative cross-coupling of aryl-, alkenyl-, and alkynylfluorosilanes promoted by fluoride ion with hypervalent aryl-, alkenyliodonium tetrafluoroborates were achieved at room temperature under an atmospheric pressure of carbon monoxide.

Diastereoselective Addition of Carbon Electrophiles to Styrylsilanes: The Dimerization of β-(E)-(Halosilyl)styrenes

β-(Halosilyl)styrenes undergo dimerization and trimerization reactions leading to 1,2,3-trisubstituted 1H-dihydroindenes with high diastereoselectivity.

The β-Effect: Changing the Ligands on Silicon

The ability of a silyl group to stabilize a carbocation β to silicon, the β-effect, is directly related to the electron-withdrawing ability of the groups on silicon.This was shown by using the degree of syn addition of bromine to (E)-β-silylstyrenes as a

An Examination of the β-Effect in an Addition Reaction with Different Ligands on Silicon

The degree of cis-addition of bromine to a series of β-silylstyrenes may be used to compare the ability of silicon atoms bearing a variety of different ligands to stabilize a β-carbocation.

SILAFUNCTIONAL COMPOUNDS IN ORGANIC SYNTHESIS. XVIII. OXIDATIVE CLEAVAGE OF THE SILICON-CARBON BOND IN ALKENYLFLUOROSILANES TO CARBONYL COMPOUNDS: SYNTHETIC AND MECHANISTIC ASPECTS

Alkenyltrifluorosilanes are readily oxidized by one equivalent of MCPBA in DMF even at -50 deg C to give the corresponding carbonyl compounds via cleavage of the carbon-silicon bond.With three equivalent of MCPBA a concomitant cleavage of the carbon-carbon bond occurs.A plausible mechanism of these new types of oxidation has been discussed.Oxidation with DABCO*2H2O2 has also been described.