83472-97-3

Upstream product

• 64888-90-0 rac-3-(4-tert-butylphenylthio)-cyclohexanone 
• 64888-90-0 (R)-3-(4-tert-butylphenylthio)-cyclohexanone 

Downstream Products

• 83473-03-4 (R)-3-(4-tert-Butyl-benzenesulfonyl)-cyclohex-3-enol 
• 83473-01-2 (S)-3-(4-tert-Butyl-benzenesulfonyl)-cyclohex-3-enol 
• 83473-02-3 (R)-3-(4-tert-Butyl-benzenesulfonyl)-cyclohex-2-enol 
• 83473-00-1 (S)-3-(4-tert-Butyl-benzenesulfonyl)-cyclohex-2-enol 
• 83472-99-5 (R)-3-(4-tert-Butyl-benzenesulfonyl)-3-phenylselanyl-cyclohexanol 
• 83472-99-5 (S)-3-(4-tert-Butyl-benzenesulfonyl)-3-phenylselanyl-cyclohexanol 
• 83510-62-7 (1R,3R)-3-(4-tert-Butyl-benzenesulfonyl)-cyclohexanol 
• 83472-98-4 (1S,3R)-3-(4-tert-Butyl-benzenesulfonyl)-cyclohexanol 

Relevant academic research and scientific papers

ASYMMETRIC SYNTHESIS OF OPTICALLY ACTIVE CYCLOHEXENOL DERIVATIVES VIA HIGHLY STEREOSELECTIVE REDUCTION OF (R)-3-(p-t-BUTYLPHENYLTHIO)CYCLOHEXAN-1-ONE

(R)-3-(p-t-Butylphenylthio)cyclohexan-1-one was reduced with LiAlH(OBut)3 to afford (1S,3R)-3-(p-t-butylphenylthio)cyclohexan-1-ol, while the same reduction with LiBH(s-Bu)3 afforded the (1R,3R) counterpart almost exclusively.Elaboration of eac

The Circular Dichroism of 3-Alkylthio- and 3-Arylthio-cyclohexanones: an Analysis of Through Bonds and Dynamic Coupling Contributions to the Optical Activity

The c.d. spectra of a series of 3-alkylthio- and 3-arylthio-cyclohexanones were recorded and interpreted by means of MO calculations and dynamic coupling approximations.From the analysis, the absolute configurations of the compounds were deduced.