83473-01-2Relevant academic research and scientific papers
ASYMMETRIC SYNTHESIS OF OPTICALLY ACTIVE CYCLOHEXENOL DERIVATIVES VIA HIGHLY STEREOSELECTIVE REDUCTION OF (R)-3-(p-t-BUTYLPHENYLTHIO)CYCLOHEXAN-1-ONE
Suzuki, Keisuke,Ikegawa, Akihiko,Mukaiyama, Teruaki
, p. 899 - 902 (2007/10/02)
(R)-3-(p-t-Butylphenylthio)cyclohexan-1-one was reduced with LiAlH(OBut)3 to afford (1S,3R)-3-(p-t-butylphenylthio)cyclohexan-1-ol, while the same reduction with LiBH(s-Bu)3 afforded the (1R,3R) counterpart almost exclusively.Elaboration of eac
