83481-29-2

Usage

Uses

Used in Pharmaceutical Research:
(1aS,4S,4aS,5aR,5bS,8aR,8bS)-5a,7,7-trimethyloctahydrocyclopropa[4,5]oxireno[6,7]indeno[5,6-c]furan-4-ol is used as a subject of pharmaceutical research for its potential biological activity and pharmacological properties. Its complex molecular structure and multiple stereoisomers offer opportunities for the development of new drugs and therapeutic agents.
Used in Medicinal Chemistry:
In the field of medicinal chemistry, (1aS,4S,4aS,5aR,5bS,8aR,8bS)-5a,7,7-trimethyloctahydrocyclopropa[4,5]oxireno[6,7]indeno[5,6-c]furan-4-ol is utilized for the exploration of its potential as a lead compound. Its unique features and chiral centers may contribute to the discovery of novel therapeutic agents with specific targeting and efficacy profiles.
Note: Since the provided materials do not specify particular applications or industries for the compound, the uses listed are general and based on the potential of the compound's structure and properties for research and development in pharmaceutical and medicinal chemistry.

Upstream product

• 143347-43-7 (1α,5α,7α,8β,12β,13α)-(+/-)-3,6-dioxa-10,10,13-trimethylpentacyclo<11.1.0.0^1,5.0^5,7.0^8,12>tetradecan-2-one 
• 126753-75-1 (1aα,3aβ,6aβ,6bα)-(+/-)-methyl 3a,4,5,6,6a,6b-hexahydro-5,5,6b-trimethyl-2<<(trifluoromethyl)sulfonyl>oxy>cyclopropindene-1a(1H)-carboxylate 
• 126753-76-2 (1aα,3aβ,6aβ,6bα)-(+/-)-dimethyl 3a,4,5,6,6a,6b-hexahydro-5,5,6b-trimethylcyclopropindene-1a,2(1H)-dicarboxylate 
• 143347-42-6 (1aα,3aβ,6aβ,6bα)-(+/-)-methyl 2-formyl-3a,4,5,6,6a,6b-hexahydro-5,5,6b-trimethyl-1H-cyclopropindene-1a-carboxylate 
• 126753-74-0 (1aα,3aβ,6aβ,6bα)-(+/-)-methyl octahydro-5,5,6b-trimethyl-2-oxopropindene-1a(1H)-carboxylate 
• 126753-73-9 cis-(+/-)-methyl 2,3,3a,6,7,7a-hexahydro-2,2,4-trimethyl-6-oxo-1H-indene-5-carboxylate 
• 143395-41-9 (1α,7β,11β,12α)-(+/-)-3-oxa-9,9,12-trimethyltetracyclo<10.1.0.0^1,5.0^7,11>tridec-5-en-2-one 
• 126753-72-8 (+/-)-4a,5,6,7-tetrahydro-1,6,6-trimethylcyclopentapyran-3(4H)-one 
• 104315-11-9 (E)-5,5,8-Trimethyl-nona-2,7-dienoic acid methyl ester 
• 104315-18-6 (+/-)-methyl 4,4-dimethyl-2-(1-methylethenyl)cyclopentaneacetate 
• 126753-71-7 (+/-)-2-acetyl-4,4-dimethylcyclopentaneacetic acid 
• 210752-27-5 4,4-dimethyl-2-isopropenylcyclopentylacetic acid 
• 86533-37-1 6-ketostearylvelutinal 
• 82855-01-4 6-stearylvelutinal 

Downstream Products

• 93943-58-9 lactardial 
• 93943-52-3 4,8-epoxy-1,3,4,4a,5,6,7,7a,8,9-decahydro-1-hydroxy-6,6,8-trimethylazuleno<5,6-c>furan 
• 93943-48-7 1,3,4,4a,5,6,7,7a,8,9-decahydro-1,4,8-trihydroxy-6,6,8-trimethylazuleno<5,6-c>furan 
• 93943-50-1 1,3,4,4a,5,6,7,7a,8,9-decahydro-1,4-dihydroxy-8-methoxy-6,6,8-trimethylazuleno<5,6-c>furan 
• 54462-53-2 lactaral 

Relevant academic research and scientific papers

Total Synthesis of Some Marasmane and Lactarane Sesquiterpenes

A general and efficient synthetic route to the marasmane sesquiterpenes (+/-)-isovelleral (2) and (+/-)-stearoylvelutinal (1b) is described.Total syntheses of two other naturally occurring sesquiterpenes, deconjugated anhydrolactarorufin A (5) and lactarorufin A (6), were achieved using an acid-catalyzed ring expansion of lactone 25.All four syntheses are highly stereoselective and do not require the use of any protecting groups.Finally, the protic acid-catalyzed degradation of velutinal (1a) was investigated in an effort to chemically induce the biologically important conversion of velutinal (1a) to isovelleral (2).The experimental results thus obtained indicate that an enzymatic mechanism for the key transformation of velutinal (1a) into isovelleral (2) is more plausible than one that is acid-catalyzed.

VELUTINAL ESTERS OF LACTARIUS VELLEREUS AND L. NECATOR. THE PREPARATION OF FREE VELUTINAL.

Esters of the pentacyclic sesquiterpene velutinal have been isolated from Lactarius species, and converted to the free alcohol by base-catalyzed transesterification in EtOH/EtO(1-).