83511-41-5Relevant academic research and scientific papers
Photochemical Transformations. 31. Photorearrangements and Photoreactions of Some Benzobicyclooctadienyl Systems
Cristol, Stanley J.,Graf, Gregor A.
, p. 5186 - 5189 (1982)
Irradiations of esters of the exo- and endo-6,7-benzobicycloocta-3,6-dien-2-ols lead only to the di-?-methane rearrangement products, even under conditions where the 3-chloro derivatives lead to photosolvolysis and Wagner-Meerwein reaction products.A tentative rationalization of the chlorine-atom effect is offered.
