Journal of Organic Chemistry p. 5186 - 5189 (1982)
Update date:2022-07-29
Topics:
Cristol, Stanley J.
Graf, Gregor A.
Irradiations of esters of the exo- and endo-6,7-benzobicyclo<3.2.1>octa-3,6-dien-2-ols lead only to the di-?-methane rearrangement products, even under conditions where the 3-chloro derivatives lead to photosolvolysis and Wagner-Meerwein reaction products.A tentative rationalization of the chlorine-atom effect is offered.
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