83521-68-0

Basic information

• Product Name: 2-(2-chlorophenyl)-1,3-dithiolane
• CAS NO: 83521-68-0
• Molecular Formula: C₉H₉ClS₂
• Molecular Weight: 216.7508
• Mol File: 83521-68-0.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 320.3°C at 760 mmHg
• Flash Point: 140.5°C
• Density: 1.323g/cm³
• Vapor Pressure: 0.000602mmHg at 25°C
• Refractive Index: 1.646
• CAS DataBase Reference: 2-(2-chlorophenyl)-1,3-dithiolane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-chlorophenyl)-1,3-dithiolane(83521-68-0)
• EPA Substance Registry System: 2-(2-chlorophenyl)-1,3-dithiolane(83521-68-0)

Safety Data

• Hazardous Substances Data: 83521-68-0(Hazardous Substances Data)

Upstream product

• 89-98-5 2-chloro-benzaldehyde 
• 540-63-6 ethane-1,2-dithiol 

Downstream Products

• 90982-75-5 phenyl o-chlorobenzenedithiocarboxylate 
• 1822-73-7 phenylthioethylene 
• 89-98-5 2-chloro-benzaldehyde 

Relevant articles and documents

Phosphorylated Polyacrylonitrile Fibers as an Efficient and Greener Acetalization Catalyst

A novel solid acid catalyst (PANEAPF) is developed by immobilization of phosphoric acid on polyacrylonitrile fiber through covalent bonding. Various characterization techniques such as elemental analysis (EA), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), etc. are utilized to confirm the successful grafting and the stability of the fiber catalysts during application. PANEAPF shows high catalytic activity in the acetalization of aldehydes owing to the high utilization efficiency of its functionalized acid sites. In addition, the strong polarity micro-environment in the surface layers of PANEAPF make it highly suitable for catalytic application in both water and alcohol. Furthermore, the fiber catalyst can be applied to the acetalization of aldehydes in a continuous-flow process at room temperature, and shows excellent reactivity and superior recyclability (over 20 times). The many advantages of PANEAPF such as simple preparation, convenient regulation of acid amount, high durability, and eco-friendly process make it very attractive for fixed-bed reactors in the chemical industry.

Aluminum hydrogen sulfate [Al(HSO4)3] as an efficient catalyst for the preparation of thioacetals

Aluminum hydrogen sulfate, as a heterogeneous solid acid catalyst, has been used for the mild conversion of carbonyl compounds to their thioacetals using 1,2- and 1,3-dithiol under ambient conditions with short reaction times in high to excellent yield in

Chemoselective dithioacetalization and oxathioacetalization of carbonyl compounds using alumina sulfuric acid as catalyst

Carbonyl compounds have been successfully converted into their corresponding dithiolane, dithiane, and oxathiolane derivatives using a catalytic amount of alumina sulfuric acid (Al2O3-SO3H) with excellent yields at room temperature in short reaction times under mild conditions. This simple method is a highly chemoselective procedure for protection of aldehydes in the presence of ketones, and the heterogeneous catalyst can be recovered and reused several times without any loss of its activity. Copyright Taylor & Francis Group, LLC.