83556-31-4Relevant academic research and scientific papers
Direct, facile synthesis of N-acyl-α-amino amides from α-keto esters and ammonia
Ntaganda, Rukundo,Milovic, Tamara,Tiburcio, Jorge,Thadani, Avinash N.
experimental part, p. 4052 - 4054 (2009/03/11)
N-Acyl-α-amino amides were prepared, without the necessity of chromatographic purification, in a single step by heating the corresponding α-keto ester in methanolic ammonia. The Royal Society of Chemistry.
Method for producing amines by homogeneously catalyzed reductive amination of carbonyl compounds
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Page/Page column 14-15, (2010/02/11)
The invention relates to the preparation of chiral or achiral amines by reaction of aldehydes or ketones with ammonia or primary or secondary amines in the presence of hydrogen and in the presence of homogeneous metal catalysts under mild conditions. Metal catalysts which can be used are complexes of late transition metals with chiral or achiral phosphorus-containing ligands.
