83558-65-0Relevant academic research and scientific papers
PREPARATION OF HOMOLEPTIC t-BUTYL ISOCYANIDE COMPLEX OF Mo(0) AND REACTIONS WITH ALKYL HALIDES. MOLECULAR STRUCTURE OF Br
Yoshida, Toshikatsu,Hirotsu, Ken,Higuchi, Taiichi,Otsuka, Sei
, p. 1017 - 1020 (1982)
Hexakis(t-butyl isocyanide)molybdenum(0) was prepared and reacted with alkyl halides to give ν2-iminoacyl Mo(II) complexes.An X-ray structural study of the product, Br revealed a distorted octahedral molecular structure, regarding the iminoacyl ligand as an unidentate ligand.An intensive bending (137 deg) of the t-butyl isocyanide trans to the ν2-iminoacyl ligand was salient.
