
Chemistry Letters p. 1017 - 1020 (1982)
Update date:2022-08-05
Topics:
Yoshida, Toshikatsu
Hirotsu, Ken
Higuchi, Taiichi
Otsuka, Sei
Hexakis(t-butyl isocyanide)molybdenum(0) was prepared and reacted with alkyl halides to give ν2-iminoacyl Mo(II) complexes.An X-ray structural study of the product, a distorted octahedral molecular structure, regarding the iminoacyl ligand as an unidentate ligand.An intensive bending (137 deg) of the t-butyl isocyanide trans to the ν2-iminoacyl ligand was salient.
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Doi:10.1055/s-2006-948210
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(1982)Doi:10.1039/d0cc03966g
(2020)Doi:10.1016/S0040-4039(00)87513-9
(1982)Doi:10.1023/B:COHC.0000027896.38910.d1
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(1983)