Chemistry Letters p. 1017 - 1020 (1982)
Update date:2022-08-05
Topics:
Yoshida, Toshikatsu
Hirotsu, Ken
Higuchi, Taiichi
Otsuka, Sei
Hexakis(t-butyl isocyanide)molybdenum(0) was prepared and reacted with alkyl halides to give ν2-iminoacyl Mo(II) complexes.An X-ray structural study of the product, a distorted octahedral molecular structure, regarding the iminoacyl ligand as an unidentate ligand.An intensive bending (137 deg) of the t-butyl isocyanide trans to the ν2-iminoacyl ligand was salient.
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(1983)
