83559-93-7Relevant articles and documents
Thermolysis of 1,5-Diazabicyclooct-2-enes, 5. - New Simple Syntheses for 4,5-Dihydro-1H-1,2-diazepines, 5,6-Dihydro-4H-1,2-diazepines, 4,5,6,7-Tetrahydro-1H-1,2-diazepines, and 1-Vinyl-1H-pyrazoles
Burgner, Klaus,Schickaneder, Helmut,Zettl, Claus
, p. 1741 - 1749 (2007/10/02)
4,4,8,8-Tetrakis(trifluoromethyl)-1,5-diazabicyclooct-2-enes on thermolysis undergo an electrocyclic ring-opening reaction or a cycloreversion process, depending on the substituent pattern of the bicyclic skeleton.With cycloelimination of 3