83566-08-9Relevant academic research and scientific papers
CONJUGATE ADDITION OF ALKYL GROUPS TO α,β-UNSATURATED SULFOXIDES VIA MICHAEL ADDITION OF NITROPARAFFINS AND SUBSEQUENT DENITRATION WITH TRIBUTYLTIN HYDRIDE
Ono, Noboru,Miyake, Hideyoshi,Kamimura, Akio,Tsukui, Nobuo,Kaji, Aritsune
, p. 2957 - 2960 (2007/10/02)
Michael addition of nitroparaffins to α,β-unsaturated sulfoxides is well effected in the presence of DBU.The nitro group in the adduct is replaced by hydrogen with Bu3SnH without influence to the sulfinyl function.The overall reactions provide an efficien
