83566-06-7Relevant academic research and scientific papers
Oxidation of organic compounds by hydrogen peroxide using polymer-anchored azo-metal catalysts
Islam, Sk. Manirul,Paul, Sumantra,Mobarok, Manir,Roy, Anupam Singha,Mondal, Paramita
, p. 7 - 14 (2013)
Polymer-anchored azo complexes of Cu(II) and Ni(II) were synthesized by the reaction of chloromethylated polystyrene, 3-aminophenol, and 1-nitroso-2-naphthol with the metal chlorides. The catalytic activities of these complexes were studied in the oxidation of various organic substrates including alkenes, alcohols, alkanes, and sulfides with 30 % aqueous hydrogen peroxide. The structures of both catalysts have been investigated by physiochemical methods. Both catalysts proved to be very stable and could be reused more than five times without significant loss of activity. Furthermore, these catalysts require very mild reaction conditions.
Exploiting Substrate Diversity for Preparing Synthetically Valuable Sulfoxides via Asymmetric Hydrogenative Kinetic Resolution
Fernández-Pérez, Héctor,Grabulosa, Arnald,Lao, Joan R.,Vidal-Ferran, Anton
supporting information, (2020/07/24)
A detailed study is disclosed on the Rh-mediated hydrogenative kinetic resolution of α,β-unsaturated sulfoxides with alkyl and aryl substituents at the α-, E- and Z-positions of the double bond. This stereoselective catalytic methodology has enabled the p
Double bond migration in S-allyl systems catalysed by [RuC1H(CO)(PPh3)3]
Ku?nik, Nikodem,Krompiec, Stanis?aw,Bieg, Tadeusz,Baj, Stefan,Skutil, Krzysztof,Chrobok, Anna
, p. 167 - 175 (2007/10/03)
Reactions of S-allyl systems (allyl sulphides of R-S-allyl type, where R = Et, allyl, Ph, Me3C, Ph3C, as well as of allyl phenyl sulphoxide, allyl phenyl sulphone, 2,5-dihydro-1,1-dioxothiophene) with [RuClH(CO) (PPh3)sub
