83567-76-4Relevant academic research and scientific papers
(DIETHYLPHOSPHINYL)DIFLUOROMETHYLLITHIUM. -PREPARATION AND SYNTHETIC APPLICATION-
Obayashi, Michio,Ito, Eiji,Matsui, Kiyohide,Kondo, Kiyosi
, p. 2323 - 2326 (2007/10/02)
The action of lithium diisopropylamide on diethyl difluoromethylphosphonate gives the title reagent which reacts with various electrophiles to introduce difluoromethylene or difluoromethyl unit.
AN IMPROVED PROCEDURE FOR THE SYNTHESIS OF 1,1-DIFLUORO-2-HYDROXYALKYLPHOSPHONATES
Obayashi, Michio,Kondo, Kiyosi
, p. 2327 - 2328 (2007/10/02)
The reaction of diethyl difluoro(trimethylsilyl)methylphosphonate with arenecarbaldehydes and aryl methyl ketones is effected with the aid of a catalyst, cesium fluoride, at room temperature to afford the title compounds.
