83567-76-4Relevant academic research and scientific papers
AN IMPROVED PROCEDURE FOR THE SYNTHESIS OF 1,1-DIFLUORO-2-HYDROXYALKYLPHOSPHONATES
Obayashi, Michio,Kondo, Kiyosi
, p. 2327 - 2328 (2007/10/02)
The reaction of diethyl difluoro(trimethylsilyl)methylphosphonate with arenecarbaldehydes and aryl methyl ketones is effected with the aid of a catalyst, cesium fluoride, at room temperature to afford the title compounds.
(DIETHYLPHOSPHINYL)DIFLUOROMETHYLLITHIUM. -PREPARATION AND SYNTHETIC APPLICATION-
Obayashi, Michio,Ito, Eiji,Matsui, Kiyohide,Kondo, Kiyosi
, p. 2323 - 2326 (2007/10/02)
The action of lithium diisopropylamide on diethyl difluoromethylphosphonate gives the title reagent which reacts with various electrophiles to introduce difluoromethylene or difluoromethyl unit.
