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5736-88-9

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5736-88-9 Usage

Chemical Properties

CLEAR YELLOW TO ORANG-RED LIQUID

Uses

4-Butoxybenzaldehyde has been used in the synthesis of:6-amino-4-(4-butoxyphenyl)-3,5-dicyanopyridine-2(1H)-thione16-(p-butoxybenzylidene)androsta-1,4-diene-3,17-dione via condensation reaction with androsta-1,4-diene-3,17-dione

Synthesis Reference(s)

The Journal of Organic Chemistry, 66, p. 2966, 2001 DOI: 10.1021/jo0056848

General Description

Kinetic constant for the inhibition of the diphenolase activity of mushroom tyrosinase by 4-butoxybenzaldehyde has been evaluated.

Check Digit Verification of cas no

The CAS Registry Mumber 5736-88-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,7,3 and 6 respectively; the second part has 2 digits, 8 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 5736-88:
(6*5)+(5*7)+(4*3)+(3*6)+(2*8)+(1*8)=119
119 % 10 = 9
So 5736-88-9 is a valid CAS Registry Number.

5736-88-9 Well-known Company Product Price

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  • Alfa Aesar

  • (A15243)  4-n-Butoxybenzaldehyde, 98%   

  • 5736-88-9

  • 10g

  • 384.0CNY

  • Detail
  • Alfa Aesar

  • (A15243)  4-n-Butoxybenzaldehyde, 98%   

  • 5736-88-9

  • 50g

  • 1133.0CNY

  • Detail

5736-88-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-Butoxybenzaldehyde

1.2 Other means of identification

Product number -
Other names Benzaldehyde, 4-butoxy-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:5736-88-9 SDS

5736-88-9Relevant articles and documents

Tuning the SOCT-ISC of bodipy based photosentizers by introducing different electron donating groups and its application in triplet-triplet-annihilation upconversion

Liang, Hui,Sun, Shanshan,Zafar, Mahmood,Yuan, Zhanxiang,Dong, Yuye,Ji, Shaomin,Huo, Yanping,Li, Ming-De,Zhao, Jianzhang

, (2020)

To study the effect of electron-donating ability on spin orbit charge transfer intersystem crossing (SOCT-ISC) efficiency, a series of bodipy derivatives (BDP-O, BDP-2-MN, BDP-2-EN) linked with electron-donating groups with different electron-donor abilities were synthesized. For BDP-2-MN and BDP-2-EN, both compounds show a sharp charge transfer emission band at 630 nm, and the local excited (LE) emission in both compounds were completely quenched due to photo-induced electron transfer (PET). By femtosecond transient absorption measurement, the triplet state population in both compounds was confirmed to occur through charge recombination (1996 ps ~2307 ps) process after the photo-induced electron transfer upon photoexcitation of bodipy moiety. A long-lived triplet excited state was observed for both compounds (lifetimes: 37 ~ 42 μs) via nanosecond transient absorption. The BDP-2-MN and BDP-2-EN can act as the triplet photosensitizers without heavy elements for the application of triplet-triplet-annihilation upconversion (TTA-UC, ΦUC can reach 4.88%). In case of BDP-O molecule, no triplet signal was observed for this compound because of poor electronic coupling between donor and acceptor. Therefore, the triplet excited state properties of bodipy chromophore was successfully regulated by adjusting electronic strength of donor moiety and implement these photosensitizers in the application of TTA-UC.

Electricity Driven 1,3-Oxohydroxylation of Donor-Acceptor Cyclopropanes: a Mild and Straightforward Access to β-Hydroxy Ketones

Banerjee, Prabal,Maajid Taily, Irshad,Saha, Debarshi

supporting information, p. 5053 - 5057 (2021/09/30)

An unprecedented external oxidant-free electrochemical protocol for 1, 3-oxohydroxylation of donor-acceptor cyclopropane is disclosed. The strategy encompasses the activation of the labile π-electron cloud of the aryl ring to cleave the strained Csp3?Csp3 bond of cyclopropane to afford the β-hydroxy ketones via insertion of molecular oxygen. More significantly, based on the detailed mechanistic investigations and cyclic voltammetry experiments, a plausible mechanism is proposed.

Light-Promoted Nickel Catalysis: Etherification of Aryl Electrophiles with Alcohols Catalyzed by a NiII-Aryl Complex

Cao, Rui,Lai, Chu-Hui,Li, Gang,Liu, Fengyi,Lu, Huan-Huan,Wang, Chao,Xiao, Jianliang,Xue, Dong,Yang, Liu,Zhang, Wei

supporting information, p. 12714 - 12719 (2020/06/02)

A highly effective C?O coupling reaction of (hetero)aryl electrophiles with primary and secondary alcohols is reported. Catalyzed by a NiII-aryl complex under long-wave UV (390–395 nm) irradiation in the presence of a soluble amine base without any additional photosensitizer, the reaction enables the etherification of aryl bromides and aryl chlorides as well as sulfonates with a wide range of primary and secondary aliphatic alcohols, affording synthetically important ethers. Intramolecular C?O coupling is also possible. The reaction appears to proceed via a NiI–NiIII catalytic cycle.

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