83569-35-1

Upstream product

• 58914-15-1 benzonitrile 2-propylide 
• 81837-94-7 4,4-dimethyl-2-phenyl-1,3-thiazole-5(4H)-thione 
• 75-15-0 carbon disulfide 
• 14491-02-2 2,2-dimethyl-3-phenyl-2H-azirine 
• 98-91-9 thiobenzoic acid 
• 81837-96-9 N-<1-(N,N-Dimethylthiocarbamoyl)-1-methylethyl>benzamid 

Relevant academic research and scientific papers

1,3-Dipolare Cycloadditionen von 2-(Benzonitrilio)-2-propanid mit 4,4-Dimethyl-2-phenyl-2-thiazolin-5-thion und Schwefelkohlenstoff

Irradiation of 2,2-dimethyl-3-phenyl-2H-azirine (11) in the presence of 4,4-dimethyl-2-phenyl-2-thiazolin-5-thione (7) yields a mixture of the three (1:1)-adducts 8, 12 and 13 (Schemes 3 and 6).The formation of 8 and 12 can be explained by 1,3-dipolar cyc

ADDITION REACTIONS WITH 1,3-THIAZOLE-5(4H)-THIONES; SYNTHESIS OF SPIROCYCLIC AND FUSED BICYCLIC SULFUR HETEROCYCLES

Various 1,6-dithiaspiro heterocycles can be synthesized from 1,3-thiazole-5(4H)-thiones via 1,3-dipolar cycloadditions, Diels-Alder reactions, ring expansion of oxiranes, and C-alkenylation followed by radical cyclization. 1,3-Thiazole-5(4H)-thiones with

1,6-DITHIA-SPIRONONADIENE AUS 2-THIAZOLIN-5-THIONEN

4,4-Dimethyl-2-phenyl-2-thiazolin-5-thione (4) reacts with 2,3-diphenylcyclopropenone (2a) at 145 deg C and with benzonitrilio-2-propanide (6) at room temperature to yield the 1,6-dithia-spirononadienes 5 and 7, respectively.