83571-73-7Relevant academic research and scientific papers
Coordination chemistry of P-rich phosphanes and silylphosphanes. XXI [1] the influence of the PR3 ligands on formation and properties of the phosphinophosphinidene complexes [{η2-tBu2P-P}Pt(PR3)
Matern, Eberhard,Pikies, Jerzy,Fritz, Gerhard
, p. 2136 - 2142 (2008/10/08)
(R3P)2PtCl2 and C2H4 yield the compounds [{η2-C2H4}Pt(PR3)2] (PR3 = PMe3, PEt3, PPhEt2, PPh2/su
Synthesis and Reactivity of Platinum-Formaldehyde Complexes
Head, Robert A.
, p. 1637 - 1640 (2007/10/02)
Sodium dihydronaphthylide reduction of (R3=Et3, Pri3, Ph3, Et2Ph, or 1/2Ph2PCH2CH2PPh2) under an ethylene atmosphere gives in quantitative yield as shown by (31)P n.m.r. spectroscopy.Reactions of the ethylene complexes with CO, CH2I2, (CF3)2CO, (CO2Et)2CO, and CH2O are described.Monomeric formaldehyde reacts to give the first platinum-formaldehyde complexes, , decomposition of which produces (n=3 or 4) and a complex tentatively assigned as .
