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SYNTHESE ASYMETRIQUE A L'AIDE D'AGENTS D'ALKYLATION A NUCLEOFUGES CHIRAUX ALKYLATION ENANTIOSELECTIVE DE LA GLYCINE
Duhamel, Pierre,Valnot, Jean-Yves,Jamal Eddine, Jamal
, p. 2863 - 2866 (1982)
Asymmetric inductions was found to take place in nucleophilic substitutions using electrophiles with chiral leaving groups.Alanine was obtained with e.e. as high as 40 percent after methylation of anion 3 by reagents 5d-f.
